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Table 3 Compares the efficiency of various methods for solvent-free condensation

From: Modified nano magnetic Fe2O3-MgO as a high active multifunctional heterogeneous catalyst for environmentally beneficial carbon–carbon synthesis

Entry

Time

Mol of cat

cat

Temperature

Yield

TON

TOF

Type of condensation

Reference

1

2 h

0.01 mol

Ammonium bicarbonate

90 °C

91%

1.365

0.068

K.C

[66]

2

1 h

0.005 mol

(1-((4-chlorophenyl) amino)-1- oxopropan-2-aminium perchlorate)

25 °C

97%

0.0194

0.0194

K.C

[67]

3

3 h

0.000006 mol

Zn(pcp)(aip). (H2O)

25 °C

99%

32.9

10.96

K.C

[68]

4

1 h

0.2 mol

1-alkyl-2,3 dimethylimida olium salts (NHC) and DBU(0.2)

80 oC

72%

0.0036

0.0036

B.C

[69]

5

12 h

0.5 mol

Imidazolium salts(NHC)/Cs2CO3

30 oC

95%

0.00475

0.0004

B.C

[70]

6

5 min

0.02 mol

BMICl/NaOMe

150 °C/microwave

97%

0.53

13.2

B.C

[71]

8

30 min

0.067 mmol

γ-Fe2O3-MgO@Ch.F

25 °C

98%

36.56

73.13

K.C

This work

9

1.5 h

0.092 mmol

γ-Fe2O3-MgO@Ch.CN

25 °C

88%

4.78

3.18

B.C

This work

  1. K.C.: Knoevenagel condensation; B.C.: Benzoin condensation