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Table 1 The developed methods’ analytical performance

From: Three techniques for the determination of perindopril through derivatization with 4-chloro-7-nitrobenzo-2-oxa-1,3-diazole

Parameter

Method I

Method II

Method III

Concentration range (µg mL−1)

5.0–60.0

0.5–6.0

1.0–10.0

Intercept (a)

0.12

62.56

9.29

Slope (b)

0.02

139.30

77.95

Correlation coefficient (r)

0.9999

0.9999

0.9999

Sy/x

2.3 × 10–3

2.93

1.72

Sa

1.6 × 10–3

2.18

1.47

Sb

1.0 × 10–4

0.64

0.22

%RSD

1.13

0.85

0.81

%Error

0.46

0.38

0.33

LOQ(µg mL−1)

1.08

0.16

0.19

LOD (µg mL−1)

0.36

0.05 0.06

 
  1. Sy/x = residuals’ SD
  2. Sa = SD of the regression lines’ intercepts
  3. Sb = SD of regression lines’ slopes
  4. % Error = RSD%/√ n
  5. LOQ = 10 Sa/b
  6. LOD = 3.3 Sa/b