HPf | [Cu(Pf)2(H2O)2].3H2O | [Cu(HPf)(bipy)(NO3)]NO3.2H2O | [Cu(HPf)(phen)(NO3)]NO3.2H2O | ||||
---|---|---|---|---|---|---|---|
(a) Bond Length (Ã…) | |||||||
 C15-O20 | 1.246 | Cu1-O1 | 2.369 | Cu1-O2 | 2.145 | Cu1-O3 | 2.249 |
 C15-O21 | 1.365 | Cu1-O2 | 1.958 | Cu1-O4 | 1.908 | Cu1-O4 | 1.993 |
 O21-H44 | 1.016 | Cu1-O3 | 1.955 | Cu1-O5 | 1.927 | Cu1-O5 | 1.944 |
 C2-O22 | 1.660 | Cu1-O4 | 2.004 | Cu1-N1 | 2.002 | Cu1-N1 | 2.0185 |
 C18-N5 | 1.495 | Cu1-O5 | 1.946 | Cu1-N6 | 2.010 | Cu1-N2 | 2.066 |
 C7-F24 | 1.407 | Cu1-O8 | 2.425 | C26-O4 | 1.337 | C14-N5 | 1.428 |
 C8-N13 | 1.397 | C17-F2 | 1.409 | C9-O5 | 1.310 | N4-C21 | 1.500 |
 C23-N17 | 1.473 | C14-F1 | 1.406 | C13-F1 | 1.404 | O6-C20 | 1.254 |
 O22–-H44 | 1.660 | O5–-H41 | 2.627 | N3-C14 | 1.501 | C13-F1 | 1.430 |
 |  | O2–-H1 | 2.712 |  |  |  |  |
(b) Bond Angle (o) | |||||||
 O1-C13-O2 | 122.39 | O1-Cu1-O2 | 73.46 | O2-Cu1-O4 | 92.53 | O3-Cu1-O4 | 87.84 |
 C13-O2-H20 | 110.87 | O1-Cu1-O3 | 109.49 | O2-Cu1-O5 | 102.56 | O3-Cu1-O5 | 110.34 |
 C12-N1-C15 | 121.50 | O1-Cu1-O4 | 86.91 | O2-Cu1-N1 | 95.88 | O3-Cu1-N1 | 97.22 |
 C11-N3-C17 | 112.98 | O1-Cu1-O5 | 109.02 | O2-Cu1-N6 | 87.43 | O3-Cu1-N2 | 90.04 |
 C5-C6-F1 | 117.72 | O1-Cu1-O8 | 174.30 | N1-Cu1-N6 | 81.54 | O4-Cu1-O5 | 91.68 |
 C7-N2-C10 | 119.66 | O2-Cu1-O3 | 91.06 | N1-Cu1-O4 | 93.57 | O4-Cu1-N1 | 174.12 |
 |  | O2-Cu1-O4 | 91.32 | N1-Cu1-O5 | 167.52 | O4-Cu1-N2 | 95.69 |
 |  | O2-Cu1-O5 | 177.12 | N6-Cu1-O4 | 167.51 | O5-Cu1-N1 | 89.34 |
 |  | O2-Cu1-O8 | 102.45 | N6-Cu1-O5 | 93.65 | O5-Cu1-N2 | 158.58 |
 |  | O3-Cu1-O4 | 163.41 | O4-Cu1-O5 | 93.34 | N1-Cu1-N2 | 81.39 |
 |  | O3-Cu1-O5 | 86.73 |  |  |  |  |
 |  | O3-Cu1-O8 | 66.21 |  |  |  |  |
 |  | O4-Cu1-O5 | 90.27 |  |  |  |  |
 |  | O4-Cu1-O8 | 97.25 |  |  |  |  |
 |  | O5-Cu1-O8 | 74.96 |  |  |  |  |