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Table 2 Synthesis of spiro-indoline-pyranochromene derivativesa

From: A novel heterogeneous acid–base nano-catalyst designed based on graphene oxide for synthesis of spiro-indoline-pyranochromene derivatives

Entry

Products

Chemical formula

M.P. (°C)

Yields (%)

4a

C20H11N3O4

290–293 (27)

95

4b

C25H22N2O6

208–212(19)

88

4c

C26H22N2O6

224–227(19)

88

4d

C26H22N2O6

257–258(19)

92

4e

C28H20N2O6

280–281(19)

93

4f

C26H24N2O6

218–220

(19)

87

4 g

C27H24N2O6

228–230 (19)

87

4 h

C29H22N2O6

233–235 (19)

90

  1. aReaction conditions: 1.0 mmol of isatin ring, nitrile moiety, 4-hydroxy coumarin and 0.04 g catalyst under solvent-free at r.t