Peak No. | Rt (min) | Compounds | Molecular formula | [M-H]− (m/z) | MS2 (m/z) | MS3 (m/z) | MS4 (m/z) | |||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
− 120 | − 90 | − 60 | -Acyla | -Acidb | -Acylhexosec | [Ag-H+84]− | [Ag-H+114]− | [Ag-H+56]− | [Ag-H+28]− | |||||
17 | 54.13 | Apig-6-C-(6″-O-fer)-β-d-glu-8-C-β-d-xyl | C36H36O17 | 739 | 618 (1) | 649 (1.6) | 679 (4) | 563 (100) | 545 (12) | 443 (1) | 353 (13) | 383 (35) | – | – |
16 | 53.83 | Apig-6-C-β-d-glu-8-C-(6″-O-fer)-β-d-glu | C37H38O18 | 769 | 649 (100) | 679 (56) | 709 (5) | 593 (17) | 575 (35) | 473 (32) | 353 (100) | 383 (14) | 325 (86) | 297 (100) |
22 | 61.74 | Apig-6-C-β-d-glu-8-C-(6″-O-3,4-dim)-β-d-glu | C38H40O18 | 783 | 663 (100) | – | 723 (5) | – | 575 (91) | 473 (48) | 353 (100) | 383 (17) | 325 (36) | 297 (100) |
23 | 63.60 | Apig-6-C-β-d-glu-8-C-(6″-O-3,4,5-trim)-β-d-glu | C39H42O19 | 813 | 693 (100) | 723 (50) | 753 (1) | – | 575 (79) | 473 (36) | 353 (100) | 383 (11) | – | – |
18 | 56.89 | Apig-6-C-α-l-ara-8-C-(6″-O-ρ-coum)β-d-glu | C35H34O16 | 709 | – | 619 (100) | 649 (54) | 563 (9) | 545 (12) | 443 (11) | 353 (100) | 383 (36) | 325 (30) | 297 (100) |
20 | 57.93 | Apig-6-C-α-l-ara-8-C-(6″-O-fer)-β-d-glu | C36H36O17 | 739 | – | 649 (100) | 679 (69) | 563 (11) | 545 (1.5) | 443 (19) | 353 (100) | 383 (16) | 325 (59) | 297 (100) |
26 | 65.01 | Apig-6-C-β-d-xyl-8-C-(6″-O-3,4-dim)-β-d-glu | C37H38O17 | 753 | – | 663 (100) | 693 (70) | – | 545 (75) | 443 (33) | 353 (100) | 383 (16) | 325 (58) | 297 (100) |
28 | 66.97 | Apig-6-C-β-d-xyl-8-C-(6″-O-3,4,5-trim)-β-d-glu | C38H40O18 | 783 | – | 693 (100) | 723 (69) | – | 545 (68) | 443 (30) | 353 (67) | 383 (2) | 325 (2) | – |
29 | 67.24 | Apig-6-C-α-l-ara-8-C-(6″-O-3,4-dim)-β-d-glu | C37H38O17 | 753 | – | 663 (100) | 693 (70) | – | 545 (95) | 443 (91) | 353 (100) | 383 (9) | 325 (100) | 297 (92) |
30 | 69.04 | Apig-6-C-α-l-ara-8-C-(6″-O-3,4,5-trim)-β-d-glu | C38H40O18 | 783 | – | 693 (100) | 723 (58) | – | 545 (74) | 443 (30) | 353 (100) | 383 (32) | 325 (99) | 297 (100) |
25 | 64.79 | Chrys-6-C-β-d-xyl-8-C-(6″-O-3,4-dim)-β-d-glu | C38H40O18 | 783 | – | 693 (79) | 723 (49) | – | 575 (72) | 473 (100) | 383 (100) | 413 (44) | 355 (37) | 327 (8) |
27 | 66.52 | Chrys-6-C-β-d-xyl-8-C-(6″-O-3,4,5-trim)-β-d-glu | C38H40O18 | 813 | – | 723 (76) | 753 (55) | – | 575 (71) | 473 (100) | 383 (100) | 413 (36) | 355 (33) | 327 (2.4) |