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Table 1 Gibbs free energy change (∆G) of twelve reaction pathways unit: Kcal/mol

From: The mechanism for enhanced oxidation degradation of dioxin-like PCBs (PCB-77) in the atmosphere by the solvation effect

Reaction type a

∆G

Reaction type b

∆G

Reaction type c

∆G

Reaction type d

∆G

a1

−3.3 × 10 −2

b1

1.0 × 10−4

c1

−9.6 × 10 −3

d1

−3.2 × 10 −2

a2

−3.6 × 10 −2

b2

4.6 × 10−3

c2

−4.6 × 10 −3

  
  

b3

1.9 × 10−2

c3

−1.1 × 10 −2

  
    

c4

−7.4 × 10 −3

  
    

c5

4.6 × 10−2

  
    

c6

1.8 × 10−2

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