Table 1 Selected bond angles (°) and bond distances (Å) for 1 and 4
Bond distance (Å) of complex 1 | Bond distance (Å) of complex 4 | ||
|---|---|---|---|
Co(1)–O(1) | 2.089(4) | Co(1)–O(1) | 2.133(7) |
Co(1)–O(1)#1 | 2.089(4) | Co(1)–O(4) | 2.117(8) |
Co(1)–O(2W)#1 | 2.100(5) | Co(1)–O(2) | 2.128(6) |
Co(1)–O(2W) | 2.100(5) | Co(1)–O(5) | 2.220(10) |
Co(1)–O(1W) | 2.141(4) | Co(1)–N(1) | 2.100(7) |
Co(1)–O(1W)#1 | 2.141(4) | Co(1)–N(2) | 2.090(7) |
Bond angle (°) of complex 1 | Bond angle (°) of complex 4 | ||
|---|---|---|---|
C(1)–O(1)–Co(1) | 126.2(4) | C(1)–O(2)–Co(1) | 91.5(5) |
O(1 W)–Co(1)–O(1W)#1 | 180.000(2) | C(21)–O(4)–Co(1) | 94.2(7) |
O(2 W)–Co(1)–O(2W)#1 | 180.000(1) | C(21)–O(5)–Co(1) | 87.6(7) |
O(1)–Co(1)–O(1)#1 | 180.000(2) | N(2)–Co(1)–N(1) | 79.8(3) |
O(1)#1–Co(1)–O(2W)#1 | 87.9(2) | N(1)–Co(1)–O(1) | 108.2(3) |
O(1)–Co(1)–O(2W) | 87.9(2) | N(2)–Co(1)–O(4) | 112.3(3) |
O(1)–Co(1)–O(1W) | 92.09(17) | N(1)–Co(1)–O(2) | 104.3(3) |
O(1)#1–Co(1)–O(1W) | 87.91(17) | N(2)–Co(1)–O(5) | 102.5(4) |
O(2W)#1–Co(1)–O(1W) | 89.4(2) | O(4)–Co(1)–O(1) | 155.4(3) |
O(2)–Co(1)–O(5) | 91.9(4) | ||
O(2)–Co(1)–O(1) | 59.1(3) | ||
C(1)–O(1)–Co(1) | 90.7(5) | ||