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Table 2 Wave numbers (cm−1) of absorption band maximums in FT-IR spectra of N-CLI, H-CLIs, and Pd(II)–Cu(II)/H-CLIs

From: Acid-modified clinoptilolite as a support for palladium–copper complexes catalyzing carbon monoxide oxidation with air oxygen

Sample

ν (OH)

δ (OH2)

T-O-T (T = Si, Al)

Other bands

νas

νsym

δ

N-CLI

3628 sh 3440

1633

1205 sh 1064

797, 778

464

1384, 604

0.25H-CLI

3624 sh 3453

1635

1205 sh 1063

797, 779

464

1399, 607

0.5H-CLI

3624 sh 3454

1635

1205 sh 1068

797, 778

459

1392, 607

1H-CLI

3622 sh 3456

1640

1208 sh 1072

798, 780

467

1531, 1384, 607

3H-CLI

3624 sh 3464

1639

1204 sh 1081

798, 780

467

1531, 1383, 608

Pd(II)–Cu(II)/0.25H-CLI

3621 sh 3446

1638

1209 sh 1064

797, 780

465

1399, 1316, 606

Pd(II)–Cu(II)/0.5H-CLI

3623 sh 3451

1634

1209 sh 1067

797, 780

464

1400, 606

Pd(II)–Cu(II)/1H-CLI

3620 sh 3446

1639

1208 sh 1072

798, 780

467

1537, 1384, 607

Pd(II)–Cu(II)/3H-CLI

3620 sh 3440

1638

1209 sh 1082

798, 780

467

1535, 1384, 607