Table 2 Hydrogen bond metrics for complexes 1-5
D---H....A | H…A (Ǻ) | D…A (Ǻ) | ∟D -H…A | Symmetry operation |
|---|---|---|---|---|
[Pb(BPY)(5-CTPC)2] (1) | ||||
C8-H8…O3 | 2.5300 | 3.334(4) | 145.00 | 3-x,1-y,2-z |
C9-H9…O1 | 2.4200 | 3.318(4) | 163.00 | 3-x,1-y,2-z |
C14-H14…O4 | 2.4700 | 3.364(4) | 162.00 | 2-x,-y,1-z |
C17-H17…O4 | 2.4700 | 3.351(4) | 158.00 | 2-x,-y,1-z |
C18-H18…O2 | 2.5300 | 3.273(4) | 137.00 | 1-x,-y,1-z |
[Pb(4-BPY)(5-CTPC)2] (2) | ||||
C9-H9…O2 | 2.56 | 3.437(4) | 157 | 2-x,1-y,-z |
[Pb2(PHEN)2(5-CTPC)4] (3) | ||||
C4-H4…Cl1 | 2.8100 | 3.617(4) | 146.00 | −2-x,-y,-z |
C11-H11…O2 | 2.5000 | 3.143(5) | 127.00 | -x,1-y,1-z |
[Pb(4-BPY)(5-BTPC)2] (4) | ||||
C22-H22A…Br1 | 2.8700 | 3.791(5) | 162.00 | 2-x,-y,2-z |
C9-H9…O2 | 2.5600 | 3.424(6) | 155.00 | 2-x,1-y,1-z |
[Pb2(PHEN)2(5-BTPC)2(ACE)2] (5) | ||||
C8-H8…O1 | 2.6000 | 3.325(5) | 135.00 | 2-x,1-y,1-z |
C8-H8…O4 | 2.4600 | 3.149(8) | 130.00 | 2-x,1-y,1-z |
C15-H15…O2 | 2.5200 | 3.109(7) | 121.00 | 2-x,1-y,2-z |