From: Detailed kinetic and chemometric study of the cellulose thermal breakdown in artificially aged and non aged commercial paper. Different methods for computing activation energy as an assessment model in archaeometric applications
Model mechanism
Symbol
Mathematical expressions
First-order decay (n=1)
F1
(1–α)
Second-order decay (n=2)
F2
(1– α)2
Third-order decay (n=3)
F3
0.5 · (1– α)3
Avrami-Erofeev (n=2)
A2
2 · (1– α) · [–ln(1– α)]0.5