Table 1 1 H and 13 C NMR spectra data of clematomandshurica saponin F (pyridine- d 5)
Position | δC/ppm | δH/ppm |
|---|---|---|
1 | 39.13 | 1.06,1,51 |
2 | 26.39 | 1.99,2.20 |
3 | 81.93 | 4.13 |
4 | 43.62 | |
5 | 47.73 | 1.67 |
6 | 18.17 | 1.26,1.28 |
7 | 32.78 | 1.51,1.52 |
8 | 39.94 | |
9 | 48.24 | 1.71 |
10 | 36.92 | |
11 | 23.39 | 1.88 |
12 | 123.72 | 5.37 |
13 | 144.12 | |
14 | 42.15 | |
15 | 28.31 | 2.20 |
16 | 23.85 | 1.99 |
17 | 47.05 | |
18 | 41.67 | 3.12,3.15 |
19 | 46.22 | 1.19,1.67 |
20 | 30.74 | |
21 | 34.03 | 1.28 |
22 | 32.57 | 1.70,1.85 |
23 | 63.96 | 4.24,3.89,CH2OH |
24 | 14.09 | 1.10,s |
25 | 16.21 | 0.94,s |
26 | 17.56 | 1.06,s |
27 | 26.07 | 1.15,s |
28 | 176.51 | |
29 | 33.11 | 0.85,s |
30 | 23.72 | 0.87,s |
3-o-sugar | ||
Ara 1 | 104.95 | 5.04 |
2 | 75.18 | 4.52 |
3 | 74.77 | 4.24 |
4 | 69.28 | 4.28 |
5 | 66.25 | 3.65,4.22 |
Rha 1 | 101.41 | 6.25,brs |
2 | 71.95 | 4.82 |
3 | 82.02 | 4.67 |
4 | 72.77 | 4.37 |
5 | 69.87 | 4.63 |
6 | 18.45 | 1.51,d,6.0Hz |
Rib 1 | 104.63 | 5.80,brs |
2 | 72.64 | 4.38 |
3 | 69.71 | 4.54 |
4 | 76.55 | 3.85 |
5 | 61.97 | 4.40 |
Glc 1 | 103.22 | 4.91,m |
2 | 74.14 | 4.28 |
3 | 76.69 | 4.28 |
4 | 81.05 | 4.63 |
5 | 75.36 | 3.91 |
6 | 61.75 | 4.20 |
Glc’ 1 | 104.85 | 5.07,d,8.1Hz |
2 | 74.24 | 3.83 |
3 | 78.37 | 4.16 |
4 | 71.95 | 4.70 |
5 | 76.80 | 4.02 |
6 | 68.57 | 3.92,4.60 |
Rha’ 1 | 102.74 | 5.40,brs |
2 | 71.75 | 4.68 |
3 | 72.56 | 4.52 |
4 | 73.89 | 4.18 |
5 | 69.75 | 4.27 |
6 | 18.52 | 1.57,d,6.0Hz |
28-o-sugar | ||
Glc” 1 | 95.65 | 6.20,d,8.0Hz |
2 | 73.83 | 4.07 |
3 | 78.75 | 4.14 |
4 | 70.95 | 4.24 |
5 | 78.05 | 4.07 |
6 | 69.28 | 4.62 |
Glc”’ 1 | 104.71 | 4.97,d,7.8Hz |
2 | 74.85 | 3.88 |
3 | 76.40 | 3.85 |
4 | 78.22 | 4.38 |
5 | 77.16 | 3.63 |
6 | 61.35 | 4.07 |
Rha” 1 | 102.76 | 5.81 |
2 | 72.56 | 4.07 |
3 | 72.83 | 4.50 |
4 | 74.09 | 3.95 |
5 | 70.32 | 4.91 |
6 | 18.62 | 1.67,d,6.1Hz |