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Table 4 Thermodynamic and kinetic parametersa of complex 3.

From: Ligand substitution reactions of a phenolic quinolyl hydrazone; oxidovanadium (IV) complexes

Stage

T (K)

A × 10-9 sec-1

E*

ΔH*

ΔG*

-ΔS*

1st

427

38.251

20.233

16.69

36.004

45.234

2nd

625

14.133

12.118

6.931

42.344

56.662

  1. a E*, ΔH* and ΔG* are in k J mol-1 while ΔS* is in J mol-1 K-1
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BMC Chemistry

ISSN: 2661-801X

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