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Table 8 Uncertainty in sampling of SPM by HVS

From: Quantifying uncertainty in the measurement of arsenic in suspended particulate matter by Atomic Absorption Spectrometry with hydride generator

Uncertainty components

Distribution

Calibration uncertainty reported in certificate

Standard uncertainty u(x)

Uncertainty in flow rate of HVS at 95% confidence level

Normal; k = 2

(Type 'B')

1.0 ± 0.2 (m3/minute)

0.2/2 = 0.1

Uncertainty due to time (in minutes) recording by time tracker recorder at 95% confidence level

Normal; k = 2

(Type 'B')

1.0 ± 0.05 (minute)

0.05/2 = 0.025

Uncertainty in ambient pressure measurement at 95% confidence level

Normal; k = 2

(Type 'B')

994.2 ± 0.6 (mbar)

0.6/2 = 0.3

Uncertainty in measuring *temperature of the site at 95% confidence level

Normal; k = 2

(Type 'B')

30 ± 3 (°C)

3/2 = 1.5

  1. Combined uncertainty due to