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Table 10 Thermodynamic functions relative to mixing process of deferiprone in the investigated mixtures at 303 K

From: Solubility and thermodynamic study of deferiprone in propylene glycol and ethanol mixture

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ΔmixG° (kJ.mol–1)

ΔmixH° (kJ.mol–1)

ΔmixS° (J.K–1.mol–1)

TΔmixS° (kJ.mol–1)

ζH

ζTS

0.00

5.56

8.26

8.90

2.70

0.754

0.246

0.10

5.20

6.74

5.06

1.53

0.815

0.185

0.20

4.81

3.42

− 4.57

− 1.39

0.712

0.288

0.30

4.46

0.83

− 11.96

− 3.62

0.187

0.813

0.40

4.13

− 0.70

− 15.95

− 4.83

0.126

0.874

0.50

3.81

− 1.67

− 18.11

− 5.49

0.234

0.766

0.60

3.52

− 2.36

− 19.40

− 5.88

0.287

0.713

0.70

3.26

− 3.97

− 23.87

− 7.23

0.354

0.646

0.80

2.98

− 3.95

− 22.86

− 6.93

0.363

0.637

0.85

2.82

− 3.19

− 19.82

− 6.01

0.347

0.653

0.90

2.92

− 3.43

− 20.97

− 6.35

0.351

0.649

1.00

3.16

− 3.92

− 23.37

− 7.08

0.357

0.643