From: Solubility and thermodynamic study of deferiprone in propylene glycol and ethanol mixture
w1 | ΔmixG° (kJ.mol–1) | ΔmixH° (kJ.mol–1) | ΔmixS° (J.K–1.mol–1) | TΔmixS° (kJ.mol–1) | ζH | ζTS |
---|---|---|---|---|---|---|
0.00 | 5.56 | 8.26 | 8.90 | 2.70 | 0.754 | 0.246 |
0.10 | 5.20 | 6.74 | 5.06 | 1.53 | 0.815 | 0.185 |
0.20 | 4.81 | 3.42 | − 4.57 | − 1.39 | 0.712 | 0.288 |
0.30 | 4.46 | 0.83 | − 11.96 | − 3.62 | 0.187 | 0.813 |
0.40 | 4.13 | − 0.70 | − 15.95 | − 4.83 | 0.126 | 0.874 |
0.50 | 3.81 | − 1.67 | − 18.11 | − 5.49 | 0.234 | 0.766 |
0.60 | 3.52 | − 2.36 | − 19.40 | − 5.88 | 0.287 | 0.713 |
0.70 | 3.26 | − 3.97 | − 23.87 | − 7.23 | 0.354 | 0.646 |
0.80 | 2.98 | − 3.95 | − 22.86 | − 6.93 | 0.363 | 0.637 |
0.85 | 2.82 | − 3.19 | − 19.82 | − 6.01 | 0.347 | 0.653 |
0.90 | 2.92 | − 3.43 | − 20.97 | − 6.35 | 0.351 | 0.649 |
1.00 | 3.16 | − 3.92 | − 23.37 | − 7.08 | 0.357 | 0.643 |