Table 1 Summary of results obtained from CV studies (pH 7.4)
Comp. | R | Epa (mV) | Epa − Epa/2 (mV) | d log Ipa/d log v (µA/mV s−1) | αn | Ks × 103 (s−1) | Г × 10−11 (mol cm−2) | Г × 1013 (molecule cm−2) |
|---|---|---|---|---|---|---|---|---|
A1 | H | 240 | 47 | 0.67 | 1.00 | 6.04 | 6.94 | 4.17 |
A2 | 4-NO2 | 282 | 57.1 | 0.75 | 0.864 | 17.39 | 8.09 | 4.87 |
A3 | 3-NO2 | 274 | 65.1 | 0.72 | 0.851 | 6.88 | 5.62 | 3.38 |
A4 | 4-F | 258 | 56.1 | 0.66 | 0.976 | 3.98 | 9.75 | 5.87 |
A5 | 4-OCF3 | 296 | 65.1 | 0.66 | 0.937 | 6.02 | 25.80 | 15.54 |
A6 | 4-CN | 264 | 63.1 | 0.78 | 0.826 | 5.24 | 8.18 | 4.93 |
A7 | 3,4-diOCH3 | 302 | 32.1 | 0.78 | 1.210 | 9.98 | 9.01 | 5.43 |
A8 | 4-CH(CH3)2 | 234 | 73.1 | 0.75 | 1.200 | 4.72 | 4.63 | 2.79 |