Peak No. | Rt (min) | Compounds | Molecular formula | [M-H]− (m/z) | MS2 (m/z)a | MS3 (m/z) | MS4 (m/z) | |||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
− 120 | − 90 | − 60 | [Ag-H+84]− | [Ag-H+114]− | [Ag-H+84]− | [Ag-H+114]− | [Ag-H+56]− | [Ag-H+28]− | [Ag-H+28-15]− | |||||
1 | 17.70 | Vicenin-II | C27H30O15 | 593 | 473 (100) | 503 (31) | – | 353 (60) | 383 (31) | 353 (100) | 383 (12) | 325 (75) | 297 (100) | – |
3 | 20.71 | Vicenin-I | C26H28O14 | 563 | 443 (61) | 473 (100) | 503 (60) | 353 (83) | 383 (56) | 353 (100) | 383 (9) | 325 (70) | 297 (100) | – |
4 | 22.10 | Schaftoside | C26H28O14 | 563 | 443 (100) | 473 (65) | 503 (5) | 353 (74) | 383 (45) | 353 (100) | 383 (20) | 325 (81) | 297 (100) | – |
5 | 22.53 | Isoschaftoside | C26H28O14 | 563 | 443 (84) | 473 (100) | 503 (69) | 353 (93) | 383 (97) | 353 (100) | 383 (19) | 325(58) | 297 (100) | – |
9 | 25.30 | Vicenin-III | C26H28O14 | 563 | 443 (100) | 473 (61) | 503 (3) | 353 (46) | 383 (32) | 353 (100) | 383 (13) | 325 (97) | 297 (100) | – |
2 | 19.15 | Chrys-6,8-di-C-β-d-glu | C28H32O16 | 623 | 503 (100) | 533 (18) | – | 383 (68) | 413 (30) | 383 (100) | 413 (28) | 355 (29) | 327 (8) | 312 (100) |
6 | 22.70 | Chrys-6-C-β-d-xyl-8-C-β-d-glu | C27H30O15 | 593 | 473 (100) | 503 (41) | 533 (26) | 383 (87) | 413 (50) | 383 (100) | 413 (44) | 355 (51) | 327 (2) | 312 (100) |
7 | 23.72 | Chrys-6-C-β-d-glu-8-C-α-l-ara | C27H30O15 | 593 | 473 (100) | 503 (36) | 533 (28) | 383 (71) | 413 (55) | 383 (100) | 413 (46) | 355 (32) | 327 (4) | 312 (100) |
8 | 24.65 | Chrys-6-C-α-l-ara-8-C-β-d-glu | C27H30O15 | 593 | 473 (90) | 503 (100) | 533 (5) | 383 (85) | 413 (36) | 383 (93) | 413 (100) | 355 (15) | 327 (7) | 312 (100) |
10b | 26.79 | Chrys-6-C-β-d-glu-8-C-β-d-xyl | C27H30O15 | 593 | 473 (77) | 503 (74) | 533 (8) | 383 (100) | 413 (47) | 383 (100, MS2) | 413 (45, MS2) | 355 (3, MS2) | 327 (4, MS3) | 312 (100, MS3) |