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Table 2 Palladium-catalyzed borylation of aryl (pseudo)halides

From: Palladium-catalyzed borylation of aryl (pseudo)halides and its applications in biaryl synthesis

  1. Reaction conditions: aryl (pseudo)halide (1.0 mmol), 10b (1.0 mol%), B2pin2 (1.2 mmol), K3PO4 (3.0 mmol), THF (2 mL), RT; isolated yield
  2. aX = I
  3. bX = Br
  4. cX = Cl
  5. dX = OTf
  6. e10b (2.0 mol%)