Table 1 Compounds identified in the Ecuadorian spirits beverages using GC × GC-QMS

1

Ethanol

x

x

x

2

2-Propanol

x

x

x

3

2-Methyl-1-propanol

x

x

x

4

2-Butanol

x

x

x

5

Ethyl acetate

x

x

x

6

n-Butanal

x

x

x

7

n-Butanol

x

x

x

8

Ethyl propanoate

x

x

x

9

2-Methyl-1-butanol

x

x

x

11

3-Methyl-1-butanol

x

x

x

12

3-Hydroxybutanal

x

x

x

14

n-Pentanol

x

x

x

15

2-Methyl-1-butanol

x

x

x

16

Hexanal

x

x

x

17

Ethyl 2-hydroxypropanoate

x

x

x

18

Furfural

x

x

x

19

n-Hexanol

x

x

x

20

Isopentyl acetate

x

x

x

21

Ethyl pentanoate

x

x

x

22

Heptanal

x

x

x

23

2-Heptanol

x

x

x

24

1-Heptanol

x

x

x

25

1S-α-Pinene

x

x

26

2-Hydroxy-3-pentanone

x

x

x

27

2(R)-Octanol

x

x

x

28

β-Pinene

x

x

29

Ethyl hexanoate

x

x

x

30

n-Octanal

x

x

x

31

Carene

x

x

32

α-Terpinene

x

x

33

p-Cymene

x

x

34

1,3,8-p-Menthatriene

x

x

35

d-Limonene

x

x

36

β-Ocimene

x

x

37

γ-Terpinene

x

x

38

2-Cyclopenten-1-one

x

x

x

39

n-Octanol

x

x

x

40

2-Nonanol

x

x

x

41

Linalool

x

x

42

Ethyl heptanoate

x

x

43

Terpinolene

x

x

44

2-Nonanone

x

x

x

45

n-Nonanal

x

x

x

46

2,4-Dimethylanisole

x

x

47

Acetophenone

x

x

48

p-Menthane

x

x

49

p-Cumenol

x

x

50

1-Nonanol

x

x

x

51

Citronellal

x

x

52

Ethyl benzoate

x

x

53

Estragole

x

x

54

Terpinen-4-ol

x

x

55

Diethyl succinate

x

x

x

56

Methyl salicylate

x

x

57

Ethyl octanoate

x

x

58

p-Propyl anisole

x

x

59

Citronellol

x

x

60

(Z)-Anethole

x

x

*

61

Geraniol

x

x

62

Phenethyl acetate

x

x

63

1-Decanol

x

x

x

64

Ethyl-non-3-enoate

x

x

x

65

(E)-Anethole

x

x

*

66

Undecen-2-ol

x

x

x

67

Undecan-2-one

x

x

x

68

Propyl octanoate

x

x

x

69

2-Undecanol

x

x

x

70

4-Propylguaiacol

x

x

71

Sec-butyl octanoate

x

x

x

72

4-Allylphenyl acetate

x

x

x

73

β-Damascenone

x

x

74

p-acetonylanisole

x

x

75

Ethyl-dec-9-enoate

x

x

x

76

Ethyl decanoate

x

x

77

n-Dodecanal

x

x

x

78

Methyl anthranilate

x

x

79

(−)-cis-α-bergamotene

x

x

*

80

β-Caryophyllene

x

x

81

3-Methylbutyl octanoate

x

x

x

82

Isopentyl octanoate

x

x

83

β-Farnesene

x

x

*

84

(−)-trans-α-bergamotene

x

*

85

α-Farnesene

x

x

*

86

n-Dodecanol

x

x

x

87

Ethyl undecanoate

x

x

88

β-Bisabolene

x

x

89

Nerolidol

x

x

90

n-Tridecanol

x

x

x

91

Ethyl dodecanoate

x

x

92

iso-Amyl n-decanoate

x

x

93

n-Tetradecanol

x

x

x

94

Foeniculin

x

x

95

α-Bisabolol

x

x

96

Ethyl tetradecanoate

x

x

x

97

Ethyl pentadecanoate

x

x

x

98

Ethyl hexadecanoate

x

x

x

99

Ethyl heptadecanoate

x

x

x

100

Ethyl octadecanoate

x

x

x