Table 2 Selected bond distances (Å) and angles (°) for 1 and 2
Within the mineral moiety | Within the organic moiety | ||
|---|---|---|---|
(C4H7N2)2[CoCl4] (1) | |||
Co1–Cl1 | 2.2741 (9) | N1A–C4A | 1.325 (5) |
Co1–Cl2 | 2.2767(10) | N1A–C2A | 1.380 (5) |
Co1–Cl3 | 2.2870 (9) | N2A–C4A | 1.327 (5) |
Co1–Cl4 | 2.2464 (9) | N2A–C3A | 1.372 (5) |
Cl2–Co1–Cl1 | 106.45 (4) | N1B–C4B | 1.331 (4) |
Cl3–Co1–Cl1 | 108.69 (3) | N1B–C2B | 1.374 (5) |
Cl3–Co1–Cl2 | 110.55 (3) | N2B–C4B | 1.331(4) |
Cl3–Co1–Cl4 | 109.09 (4) | N2B–C3B | 1.370 (5) |
Cl2–Co1–Cl4 | 110.16 (4) | C2A–C3A | 1.345(5) |
Cl1–Co1–Cl4 | 111.87 (3) | C4A–C5A | 1.479 (6) |
C2B–C3B | 1.348 (5) | ||
C4B–C5B | 1.478 (5) | ||
C4A–N1A–C2A | 110.0 (3) | ||
C4A–N2A–C3A | 110.1 (3) | ||
C4B–N2B–C3B | 110.2 (3) | ||
C4A–N2A–C3A | 110.1 (3) | ||
C3B–C2B–N1B | 106.5 (3) | ||
C3A–C2A–N1A | 106.3 (3) | ||
C2B–C3B–N2B | 106.7 (3) | ||
C2A–C3A–N2A | 106.8 (3) | ||
N1A–C4A–N2A | 106.8 (3) | ||
N1A–C4A–C5A | 126.5 (4) | ||
N2A–C4A–C5A | 126.7 (4) | ||
N1B–C4B–N2B | 106.5 (3) | ||
N1B–C4B–C5B | 126.8 (3) | ||
N2B–C4B–C5B | 126.6 (3) | ||
(C4H7N2)2[ZnCl4] (2) | |||
Zn–Cl1 | 2.2780 (11) | N1A–C2A | 1.325 (5) |
Zn–Cl2 | 2.2779 (13) | N1A–C3A | 1.381 (6) |
Zn–Cl3 | 2.2392 (16) | N2A–C2A | 1.335 (5) |
Zn–Cl4 | 2.2945 (13) | N2A–C4A | 1.386 (6) |
Cl2–Zn–Cl1 | 106.45 (5) | C1A–C2A | 1.438 (6) |
Cl3–Zn–Cl1 | 112.11 (4) | C3A–C4A | 1.347 (6) |
Cl3–Zn–Cl2 | 110.49 (5) | N1B–C2B | 1.336 (5) |
Cl3–Zn–Cl4 | 109.43 (5) | N1B–C3B | 1.372 (6) |
Cl2–Zn–Cl4 | 109.98 (4) | N2B–C2B | 1.332 (5) |
Cl1–Zn–Cl4 | 108.31 (4) | N2B–C4B | 1.380 (6) |
C1B–C2B | 1.471 (6) | ||
C3B–C4B | 1.348 (6) | ||
C3A–C4A–N2A | 106.7 (4) | ||
C2A–N2A–C4A | 109.8 (3) | ||
N1A–C2A–N2A | 106.8 (4) | ||
N1A–C2A–C1A | 126.6 (4) | ||
N2A–C2A–C1A | 126.6 (4) | ||
C4A–C3A–N1A | 106.7 (4) | ||
C2B–N1B–C3B | 110.3 (4) | ||
C2B–N2B–C4B | 110.3 (3) | ||
N2B–C2B–N1B | 106.2 (4) | ||
N2B–C2B–C1B | 126.6 (4) | ||
N1B–C2B–C1B | 127.2 (4) | ||
C4B–C3B–N1B | 106.8 (4) | ||
C3B–C4B–N2B | 106.4 (4) | ||