Table 3 Characteristics of bioactive components in various tissues

1

2.63

313.0718 [M−H]⁻

C₁₇H₁₄O₆

Salvianolic acid F^b

2

3.59

535.1818 [M−H]⁻

C₂₆H₃₂O₁₂

(+)1-hydroxypinoresinol-1-O-β-D-glucoside^b

3

3.96

359.0732 [M−H]⁻

C₁₈H₁₆O₈

Rosmarinic acid^b

4

4.43

717.1406 [M−H]⁻

C₃₆H₃₀O₁₆

Salvianolic acid B^c

5

4.56

137.0242 [M−H]⁻

C₇H₆O₃

Protocatechualdehyde^b

6

4.98

193.0479 [M−H]⁻

C₁₀H₁₀O₄

Ferulic acid^b

7

6.04

335.0894 [M+Na]⁺, 313.1071 [M+H]⁺

C₁₈H₁₆O₅

Tanshindiol C^b

8

7.18

297.1118 [M−H]⁻

C₁₉H₂₂O₃

Arucadiol^b

9

7.40

319.0944 [M+Na]⁺, 297.1124 [M+H]⁺

C₁₈H₁₆O₄

Danshenxinkun^b

10

7.63

117.0193 [M−H]⁻

C₄H₆O₄

Succinic acid^b

11

7.77

357.0588 [M−H]⁻

C₁₈H₁₄O₈

Prolithospermic acid^b

12

7.84

335.1252 [M + Na]⁺, 313.1432 [M+H]⁺

C₁₉H₂₀O₄

Miltionone II^b

13

8.99

317.0786 [M+Na]⁺, 295.0969 [M+H]⁺

C₁₈H₁₄O₄

Trijuganone A^b

14

9.12

319.0944 [M+Na]⁺, 297.1124 [M+H]⁺

C₁₈H₁₆O₄

Tanshinone VI^b

15

9.27

383.9794 [M−H]⁻

Unknown

16

9.98

333.1097 [M+Na]⁺, 311.1279 [M+H]⁺

C₁₉H₁₈O₄

Isotanshinone^b

17

10.07

303.0996 [M+Na]⁺, 281.1162 [M+H]⁺

C₁₈H₁₆O₃

Methylene dihydrotanshinone^b

18

10.21

335.1252 [M+Na]⁺, 313.1434 [M+H]⁺

C₁₉H₂₀O₄

Miltionone I^b

19

10.35

491.1039 [M−H]⁻

C₂₆H₂₀O₁₀

Salvianolic acid C^b

20

10.41

333.1098 [M+Na]⁺, 311.1282 [M+H]⁺

C₁₉H₁₈O₄

Tanshinone II ^b_B

21

10.64

333.1100 [M+Na]⁺, 311.1282 [M+H]⁺

C₁₉H₁₈O₄

3α-hydroxytanshinone II_A/3β-hydroxytanshinone II ^b_A

22

10.87

333.1099 [M+Na]⁺, 311.1283 [M+H]⁺

C₁₉H₁₈O₄

3α-hydroxytanshinone II_A/3β-hydroxytanshinone II ^b_A

23

10.98

327.0872 [M−H]⁻

C₁₈H₁₆O₆

Methylsalvianolate F^b

24

11.38

363.1202 [M+Na]⁺, 341.1380 [M+H]⁺

C₂₀H₂₀O₅

Cryptomethyltanshinoate^b

25

11.57

295.0958 [M−H]⁻

C₁₈H₁₆O₄

Tanshinol B^b

26

11.75

325.1079 [M−H]⁻

C₁₄H₁₄O₉

Monocaffeoyltartaric acid^b

27

12.01

285.1853 [M−H]⁻

C₂₀H₃₀O

Ferruginol^b

28

12.02

309.1125 [M+Na]⁺, 287.1642 [M+H]⁺

C₁₈H₂₂O₃

Epicryptoacetalide/Cryptoacetalide^b

29

12.18

487.3401 [M−H]⁻

Unknown

30

12.24

309.1125 [M+Na]⁺, 287.2002 [M+H]⁺

C₁₈H₂₂O₃

Epicryptoacetalide/Cryptoacetalide^b

31

12.35

313.1438 [M−H]⁻

C₁₉H₂₂O₄

Tanshinone V^b

32

12.38

301.0838 [M+Na]⁺, 279.1016 [M+H]⁺

C₁₈H₁₄O₃

Methylenetanshinquinone^b

33

12.46

485.3274 [M−H]⁻

Unknown

34

12.57

537.1038 [M−H]⁻

C₂₇H₂₂O₁₂

Lithospermic acid^b

35

12.82

293.0819 [M−H]⁻

C₁₈H₁₄O₄

3-hydroxymethylenetanshinone^b

36

12.88

321.1646 [M+Na]⁺, 299.1642 [M+H]⁺

C₁₉H₂₂O₃

Miltiodiol^b

37

12.96

555.3268 [M−H]⁻

Unknown

38

13.00

301.0834 [M+Na]⁺, 279.1015 [M+H]⁺

C₁₈H₁₄O₃

Dihydrotanshinone I^c

39

13.11

301.0834 [M+Na]⁺, 279.1015 [M+H]⁺

C₁₈H₁₄O₃

1,2-dihydrotanshinone I^b

40

13.16

329.1750 [M−H]⁻

C₂₀H₂₆O₄

Salviol^b

41

13.41

319.1306 [M+Na]⁺, 297.1491 [M+H]⁺

C₁₉H₂₀O₃

Isocryptotanshinone^b

42

13.84

303.0998 [M+Na]⁺, 281.1173 [M+H]⁺

C₁₈H₁₆O₃

Danshenxinkun B^b

43

14.25

361.1045 [M+Na]⁺, 339.1230 [M+H]⁺

C₂₀H₁₈O₅

Methyl tanshinoate^b

44

14.32

357.0616 [M−H]⁻

C₁₈H₁₄O₈

Prolithospermic acid^b

45

14.62

333.1089 [M+Na]⁺, 301.1800 [M+H]⁺

C₁₉H₂₄O₃

Miltipolone^b

46

14.75

265.1470 [M−H]⁻

C₁₈H₁₈O₂

Methylenemiltirone^b

47

15.45

315.0846 [M−H]⁻

C₁₇H₁₆O₆

5,3′-dihydroxy-7,4′-dimethoxyflavanone^b

48

15.97

299.0684 [M+Na]⁺, 277.0867 [M+H]⁺

C₁₈H₁₂O₃

Tanshinone I^c

49

16.00

319.1307 [M+Na]⁺, 297.1488 [M+H]⁺

C₁₉H₂₀O₃

Cryptotanshinone^c

50

16.15

315.1949 [M−H]⁻

C₂₀H₂₈O₃

1-​phenanthrenecarboxyl​ic acid^b

51

16.35

297.1830 [M−H]⁻

C₂₀H₂₆O₂

5-​dehydrosugiol^b

52

16.64

299.2018 [M−H]⁻

C₂₀H₂₈O₂

Sugiol^b

53

16.79

299.0684 [M+Na]⁺, 277.0867 [M+H]⁺

C₁₈H₁₂O₃

Isotanshinone I^b

54

17.25

301.0834 [M+Na]⁺, 279.1015 [M + H]⁺

C₁₈H₁₄O₃

Dihydroisotanshinone I^b

55

17.75

315.1001 [M+Na]⁺, 293.1179 [M+H]⁺

C₁₉H₁₆O₃

1,2 -didehydrotanshinone II ^b_A

56

18.18

289.1204 [M+Na]⁺, 267.1386 [M+H]⁺

C₁₇H₁₄O₃

Dihydrotanshinlactone^b

57

18.87

303.1306 [M+Na]⁺, 281.1539 [M+H]⁺

C₁₉H₂₀O₂

Δ¹ -dehydromiltirone^b

58

19.13

325.1824 [M−H]⁻

C₂₁H₂₆O₃

2-(7-Dihydroxyl)-benzofuranyl-,ferulic acid^b

59

19.30

317.1158 [M+Na]⁺, 295.1333 [M+H]⁺

C₁₉H₁₈O₃

Tanshinone II ^c_A

60

20.01

317.1151 [M+Na]⁺, 295.1332 [M+H]⁺

C₁₉H₁₈O₃

Isotanshinone II ^b_A

61

20.39

305.1515 [M+Na]⁺, 283.1700 [M+H]⁺

C₁₉H₂₂O₂

Miltirone^b

62

21.31

683.4317 [M−H]⁻

C₄₄H₆₀O₆

3,4-Dihydroxy-(1α,3α,4α,5β)-1-carboxy-4-hydroxy-1,3,5-cyclohexanetriyl ester-benzenepropanoic^b