Table 3 Selected bond distances (Å) and bond angles (°) of complex 1
Atoms | Length | Atoms | Length |
|---|---|---|---|
Cd1-N14 | 2.346 (2) | C12-N13 | 1.472 (4) |
Cd1-N20 | 2.357 (2) | N14-C15 | 1.475 (4) |
Cd1-N7 | 2.365 (3) | C15-C16 | 1.516 (4) |
Cd1-N13 | 2.365 (3) | C16-N17 | 1.469 (4) |
Cd1-N17 | 2.410 (2) | N17-C18 | 1.471 (4) |
Cd1-N10 | 2.422 (3) | C18-C19 | 1.512 (4) |
N7-C8 | 1.474 (4) | C19-N20 | 1.476 (4) |
C8-C9 | 1.517 (5) | Cd2-Br5 | 2.5721 (5) |
C9-N10 | 1.463 (4) | Cd2-Br4 | 2.5809 (5) |
N10-C11 | 1.468 (4) | Cd2-Br6 | 2.5835 (4) |
C11-C12 | 1.514 (5) | Cd2-Br3 | 2.6313 (5) |
Atoms | Angle | Atoms | Angle |
|---|---|---|---|
N14-Cd1-N20 | 141.05 (9) | C11-N10-Cd1 | 107.43 (19) |
N14-Cd1-N7 | 88.75 (9) | N10-C11-C12 | 109.8 (3) |
N20-Cd1-N7 | 90.10 (9) | N13-C12-C11 | 110.7 (3) |
N14-Cd1-N13 | 91.91 (9) | C12-N13-Cd1 | 111.76 (19) |
N20-Cd1-N13 | 111.72 (9) | C15-N14-Cd1 | 108.88 (18) |
N7-Cd1-N13 | 142.31 (9) | N14-C15-C16 | 109.2 (3) |
N14-Cd1-N17 | 74.73 (8) | N17-C16-C15 | 110.1 (3) |
N20-Cd1-N17 | 74.29 (9) | C16-N17-C18 | 114.7 (2) |
N7-Cd1-N17 | 125.05 (9) | C16-N17-Cd1 | 107.94 (18) |
N13-Cd1-N17 | 91.21 (9) | C18-N17-Cd1 | 107.01 (18) |
N14-Cd1-N10 | 121.49 (9) | N17-C18-C19 | 109.7 (3) |
N20-Cd1-N10 | 95.39 (9) | N20-C19-C18 | 109.4 (3) |
N7-Cd1-N10 | 73.99 (9) | C19-N20-Cd1 | 110.46 (18) |
N13-Cd1-N10 | 73.68 (9) | Br5-Cd2-Br4 | 109.305 (14) |
N17-Cd1-N10 | 157.38 (9) | Br5-Cd2-Br6 | 108.258 (14) |
C8-N7-Cd1 | 110.03 (19) | Br4-Cd2-Br6 | 111.585 (14) |
N7-C8-C9 | 109.8 (3) | Br5-Cd2-Br3 | 111.083 (13) |
N10-C9-C8 | 110.6 (3) | Br4-Cd2-Br3 | 104.874 (13) |
C9-N10-C11 | 114.8 (3) | Br6-Cd2-Br3 | 111.720 (16) |
C9-N10-Cd1 | 108.82 (19) | Â | Â |