Skip to main content

Table 3 Limits of detection (LOD) in ng L−1 obtained for all water matrices tested

From: Analysis of steroid hormones and their conjugated forms in water and urine by on-line solid-phase extraction coupled to liquid chromatography tandem mass spectrometry

Estrogens

LOD (in ng L−1)a

HPLC 1 mLb

DW 1 mLb

RW 1 mLb

WW 1 mLb

HPLC 5 mLb

RW 5 mLb

E3-3S

7.1

13

7.1

41

9.2

6.3

E2-17G

27

21

48

42

14

21

E2-17S

6.9

17

8.2

28

4.7

3.3

E1-3S

25

63

74

76

4.6

27

E2-3S

8.9

14

5.0

13

3.4

5.3

E3

37

59

26

52

3.6

10

E2

19

14

9.7

14

6.1

9.5

E1

32

20

5.0

26

13

9.7

EE2

31

46

49

62

7.2

25

  1. DW drinking water, RW river water, WW wastewater
  2. aLOD—limit of detection, determined using the most abundant product ion
  3. bSample volume