Table 5 The thermal decomposition of carbon – bonded anionic sigma complexes (1 – 3)
Complex | Stage | Activation energy kJ/mol (kcal/mol) | |
|---|---|---|---|
Using Ozawa method | Using Kissinger’s method | ||
1 | I | 81(19) | 80(19) |
II | 54(13) | 47(11) | |
2 | I | 225(53) | 229(54) |
II | 105(24) | 100(24) | |
3 | I | 101(24) | 100(24) |
II | 156(37) | 158(37) | |