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Table 2 Selected bond lengths (Å) and angles (°) for 1a and 1b

From: Thermal decomposition of [Co(en)3][Fe(CN)6]∙ 2H2O: Topotactic dehydration process, valence and spin exchange mechanism elucidation

1a

 

1b

 

Co1–N7

1.955(2)

Co1–N4

1.964(2)

Co1–N8

1.977(2)

Co1–N5

1.963(2)

Co1–N9

1.978(2)

Co1–N6

1.966(2)

Co1–N10

1.981(2)

Co1–N7

1.956(2)

Co1–N11

1.971(2)

Co1–N8

1.968(2)

Co1–N12

1.968(2)

Co1–N9

1.966(2)

Fe1A–C1A

1.941(3)

Fe1A–C1A

1.947(3)

Fe1A–C2A

1.932(3)

Fe1A–C2A

1.927(3)

Fe1A–C3A

1.946(3)

Fe1A–C3A

1.944(3)

Fe1–C1

1.951(3)

Fe1–C1

1.941(3)

Fe1–C2

1.948(3)

Fe1–C2

1.946(3)

Fe1–C3

1.944(3)

Fe1–C3

1.928(3)

N7–Co–N8

85.59(9)

N4–Co–N5

85.40(9)

N9–Co–N10

84.82(9)

N6–Co–N7

85.74(9)

N11–Co–N12

85.67(9)

N9–Co–N8

85.55(9)