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Table 2 The analytical performance data of the proposed LC-MS method

From: Atropisomeric determination of chiral hydroxylated metabolites of polychlorinated biphenyls using HPLC-MS

Compound

Calibration curve

Correlation coefficient

Detection limit

RSD

(ng mL-1)

(%, n = 5)a

E1-5OH-PCB91

Y = 8697.4×-2090.9

0.9998

0.30

1.31

E2-5OH-PCB91

Y = 9261.9×-2124.1

0.9997

0.31

0.60

E1-4OH-PCB91

Y = 4831.3×-1493.0

0.9998

0.54

0.67

E2-4OH-PCB91

Y = 5009.9×-1607.8

0.9998

0.60

1.14

E1-5OH-PCB95

Y = 6172.1×-3904.2

0.9997

0.44

7.55

E2-5OH-PCB95

Y = 3822.2×-2213.2

0.9996

0.56

6.87

E1-4OH-PCB95

Y = 5275.7×-1726.8

0.9998

0.49

3.12

E2-4OH-PCB95

Y = 5371.7×-1728.8

0.9997

0.55

3.45

E1-5OH-PCB149

Y = 6502.2×-2647.4

0.9998

0.53

0.99

E2-5OH-PCB149

Y = 4969.6×-624.2

0.9999

0.60

3.37

  1. a, All standard concentration, 10.0 ng mL-1.