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Table 4 Metals and metalloids content in various tobacco products

From: Quantitative analysis of some important metals and metalloids in tobacco products by inductively coupled plasma-mass spectrometry (ICP-MS)

Code Amount of element μg/g ± S.D.
Al Cr Mn Fe Co Ni Cu Zn As Se Cd Pb
Smoked tobacco products
T1 820 ± 5.00 3.10 ± 0.02 110 ± 0.90 1200 ± 8.46 0.83 ± 0.01 3.92 ± 0.10 24.5 ± 0.11 38.6 ± 0.15 0.65 ± 0.02 BDL 0.68 ± 0.01 1.42 ± 0.01
T2 360 ± 0.50 1.49 ± 0.05 145 ± 0.30 460 ± 0.41 0.51 ± 0.02 2.36 ± 0.06 23.0 ± 0.06 34.0 ± 0.20 0.40 ± 0.02 0.29 ± 0.01 0.80 ± 0.04 0.65 ± 0.01
T3 1000 ± 1.47 3.53 ± 0.05 120 ± 0.15 1500 ± 0.75 1.00 ± 0.01 3.94 ± 0.11 34.0 ± 0.20 45.0 ± 0.25 0.77 ± 0.12 BDL 0.61 ± 0.02 1.89 ± 0.01
T4 603 ± 1.33 3.21 ± 0.06 90.4 ± 0.10 905 ± 3.55 0.64 ± 0.03 4.19 ± 0.20 18.8 ± 0.20 26.5 ± 0.23 0.91 ± 0.09 1.25 ± 0.06 0.54 ± 0.03 1.09 ± 0.05
T5 635 ± 14.30 2.76 ± 0.05 199.6 ± 0.4 872 ± 18.20 0.78 ± 0.01 3.94 ± 0.26 22.4 ± 0.36 34.4 ± 1.19 0.63 ± 0.02 BDL 1.10 ± 0.05 1.59 ± 0.05
T6 870 ± 5.50 3.52 ± 0.02 131.1 ± 0.3 1300 ± 5.70 0.90 ± 0.01 4.26 ± 0.05 23.8 ± 0.15 33.9 ± 0.10 0.87 ± 0.04 0.64 ± 0.21 0.66 ± 0.03 1.29 ± 0.01
T7 588 ± 2.78 2.45 ± 0.05 170 ± 0.92 790 ± 1.21 0.68 ± 0.01 2.24 ± 0.15 16.43 ± 0.1 35.4 ± 0.17 0.39 ± 0.05 BDL 1.00 ± 0.02 0.92 ± 0.01
T8 1150 ± 16.00 3.44 ± 0.05 105 ± 1.47 1400 ± 17.7 0.81 ± 0.01 3.61 ± 0.07 24.2 ± 0.30 36.7 ± 3.21 0.87 ± 0.07 0.66 ± 0.14 0.52 ± 0.01 1.18 ± 0.05
T9 517 ± 6.39 1.92 ± 0.09 142 ± 1.59 724 ± 5.09 0.64 ± 0.02 2.33 ± 0.20 15.75 ± 0.1 32.9 ± 0.10 0.89 ± 0.11 1.60 ± 0.14 1.22 ± 0.10 0.78 ± 0.01
T10 803 ± 8.82 3.17 ± 0.05 103 ± 0.75 1200 ± 9.53 0.85 ± 0.01 4.15 ± 0.15 26.9 ± 0.15 38.4 ± 0.43 0.81 ± 0.09 0.24 ± 0.09 0.63 ± 0.05 1.37 ± 0.05
T11 507 ± 15.60 3.07 ± 0.05 76.8 ± 0.26 840 ± 1.20 0.58 ± 0.01 2.33 ± 0.10 21.9 ± 0.05 29.5 ± 0.05 0.57 ± 0.09 0.17 ± 0.18 0.36 ± 0.03 1.01 ± 0.01
T12 894.8 ± 30.40 2.05 ± 0.14 66.12 ± 1.9 886.8 ± 28 0.44 ± 0.02 2.18 ± 0.21 20.7 ± 0.75 32.44 ± 1.4 1.08 ± 0.21 0.50 ± 0.12 0.3 ± 0.025 0.87 ± 0.05
T13 488 ± 3.70 3.00 ± 0.05 232 ± 0.20 623 ± 1.34 0.84 ± 0.02 2.52 ± 0.10 21.5 ± 0.05 52.5 ± 0.20 0.65 ± 0.12 0.62 ± 0.15 1.23 ± 0.03 0.61 ± 0.01
T14 520 ± 4.51 3.06 ± 0.10 78.9 ± 0.66 832 ± 8.17 0.60 ± 0.01 2.27 ± 0.15 16.5 ± 0.15 24.5 ± 0.15 0.51 ± 0.07 0.062 ± 0.1 0.43 ± 0.01 0.98 ± 0.02
T15 399 ± 0.60 2.08 ± 0.10 167 ± 0.10 541 ± 1.73 0.54 ± 0.01 2.27 ± 0.17 15.2 ± 0.11 35.8 ± 0.25 0.61 ± 0.10 0.73 ± 0.07 1.76 ± 0.03 1.08 ± 0.10
T16 1310 ± 12.20 4.25 ± 0.05 143 ± 1.65 1870 ± 21.8 1.30 ± 0.02 4.67 ± 0.05 21.9 ± 0.20 37.9 ± 0.25 1.00 ± 0.10 BDL 0.54 ± 0.03 1.72 ± 0.01
T17 1420 ± 5.60 4.19 ± 0.05 122 ± 0.45 1480 ± 7.70 0.85 ± 0.01 3.30 ± 0.10 22.0 ± 0.10 37.5 ± 0.10 0.81 ± 0.07 0.21 ± 0.04 0.47 ± 0.02 1.29 ± 0.02
T18 886 ± 9.12 2.93 ± 0.02 109.7 ± 1.0 935 ± 10.80 0.68 ± 0.01 3.06 ± 0.10 20.5 ± 0.06 29.8 ± 0.10 0.50 ± 0.01 BDL 0.73 ± 0.03 1.22 ± 0.01
T19 640 ± 1.00 3.50 ± 0.10 104 ± 0.45 1030 ± 2.12 0.74 ± 0.02 2.61 ± 0.26 19.0 ± 0.17 29.7 ± 0.55 0.86 ± 0.03 0.47 ± 0.04 0.45 ± 0.04 1.06 ± 0.05
T20 566 ± 1.90 2.93 ± 0.05 89.3 ± 0.15 844 ± 2.02 0.63 ± 0.01 2.25 ± 0.23 19.2 ± 0.20 27.0 ± 0.23 0.51 ± 0.04 BDL 0.50 ± 0.03 0.99 ± 0.01
T21 865 ± 7.75 3.67 ± 0.05 103 ± 1.21 1300 ± 12.5 0.84 ± 0.01 2.69 ± 0.06 19.2 ± 0.10 30.2 ± 0.25 0.94 ± 0.10 1.06 ± 0.21 0.55 ± 0.01 1.29 ± 0.01
T22 642 ± 5.43 2.79 ± 0.06 93.0 ± 0.72 887 ± 8.63 0.72 ± 0.01 2.72 ± 0.10 20.3 ± 0.10 27.0 ± 0.26 0.69 ± 0.12 0.64 ± 0.07 0.49 ± 0.03 1.00 ± 0.01
T23 449 ± 7.09 2.17 ± 0.05 118 ± 2.04 647 ± 10.03 0.70 ± 0.01 2.40 ± 0.05 20.4 ± 0.30 32.0 ± 0.43 0.46 ± 0.06 0.27 ± 0.05 0.74 ± 0.03 1.18 ± 0.05
T24 633 ± 6.59 2.90 ± 0.06 145 ± 1.02 967 ± 7.55 0.81 ± 0.01 3.66 ± 0.06 19.9 ± 0.15 35.3 ± 0.10 0.96 ± 0.10 1.10 ± 0.07 0.74 ± 0.03 1.19 ± 0.10
T25 669 ± 3.41 2.62 ± 0.05 91.96 ± 0.4 907 ± 0.85 0.68 ± 0.01 2.39 ± 0.10 19.0 ± 0.15 27.0 ± 0.20 0.60 ± 0.07 BDL 0.44 ± 0.01 1.06 ± 0.03
T26 382 ± 0.62 2.19 ± 0.10 170 ± 0.10 570 ± 1.96 0.86 ± 0.01 5.09 ± 0.09 21.5 ± 0.37 47.0 ± 0.70 0.60 ± 0.03 0.34 ± 0.04 1.27 ± 0.04 0.57 ± 0.01
I1 710 ± 2.52 1.84 ± 0.07 223 ± 1.06 600 ± 1.05 0.93 ± 0.01 2.23 ± 0.05 14.9 ± 0.11 53.3 ± 0.23 0.33 ± 0.01 BDL 0.96 ± 0.03 0.64 ± 0.01
I2 150 ± 1.10 1.68 ± 0.05 260 ± 2.53 190 ± 1.36 0.65 ± 0.01 1.92 ± 0.07 10.5 ± 0.11 52.6 ± 0.20 1.16 ± 0.28 2.28 ± 0.28 1.49 ± 0.07 1.03 ± 0.02
I3 320 ± 1.94 2.36 ± 0.05 225 ± 1.93 460 ± 2.08 0.89 ± 0.01 3.76 ± 0.15 17.4 ± 0.11 50.4 ± 0.05 0.82 ± 0.13 0.99 ± 0.02 3.35 ± 0.05 2.52 ± 0.01
I4 620 ± 1.57 1.66 ± 0.05 270 ± 8.67 570 ± 3.55 0.90 ± 0.02 2.43 ± 0.05 16.0 ± 0.11 42.2 ± 0.15 0.72 ± 0.06 0.39 ± 0.02 2.70 ± 0.01 2.36 ± 0.05
I5 300 ± 3.81 2.03 ± 0.05 200 ± 2.90 530 ± 6.35 0.76 ± 0.01 8.07 ± 0.05 15.0 ± 0.30 32.2 ± 0.32 0.38 ± 0.02 BDL 1.46 ± 0.06 0.56 ± 0.01
I6 330 ± 4.73 1.55 ± 0.05 300 ± 13.60 390 ± 3.15 1.03 ± 0.01 2.58 ± 0.10 17.0 ± 0.15 55.6 ± 0.40 0.72 ± 0.27 1.10 ± 0.10 3.20 ± 0.05 1.55 ± 0.05
B1 360 ± 3.50 1.70 ± 0.03 53 ± 0.25 440 ± 3.36 0.52 ± 0.02 3.70 ± 0.08 11.0 ± 0.24 38.0 ± 0.11 1.30 ± 0.28 0.73 ± 0.18 0.27 ± 0.03 0.79 ± 0.01
B2 1900 ± 30.20 3.90 ± 0.10 89.9 ± 1.19 1600 ± 20.0 0.88 ± 0.03 3.60 ± 0.07 13.0 ± 0.05 31.0 ± 0.40 0.74 ± 0.09 0.89 ± 0.13 0.37 ± 0.01 1.32 ± 0.03
B3 2100 ± 5.66 5.37 ± 0.10 140 ± 0.34 2600 ± 7.69 1.31 ± 0.02 4.47 ± 0.10 13.7 ± 0.14 45.7 ± 0.72 1.53 ± 0.18 1.16 ± 0.09 0.50 ± 0.08 2.00 ± 0.01
Sniffing tobacco products
N1 1496 ± 9.28 6.33 ± 0.05 83.6 ± 0.10 1940 ± 14.2 0.98 ± 0.01 4.87 ± 0.13 12.8 ± 0.05 34.9 ± 0.20 0.87 ± 0.10 0.52 ± 0.09 0.42 ± 0.02 2.38 ± 0.01
N2 2080 ± 15.00 6.86 ± 0.04 82.3 ± 0.51 2220 ± 8.57 0.93 ± 0.01 5.07 ± 0.09 16.6 ± 0.05 40.8 ± 0.15 0.90 ± 0.07 0.59 ± 0.01 0.46 ± 0.01 2.07 ± 0.02
N3 1500 ± 19.67 7.14 ± 0.13 79.2 ± 0.73 1980 ± 19.4 0.93 ± 0.01 6.32 ± 0.30 13.6 ± 0.23 34.9 ± 0.51 0.77 ± 0.18 BDL 0.42 ± 0.01 3.99 ± 0.05
Dipping tobacco products
N4 1000 ± 4.81 2.89 ± 0.03 41.5 ± 0.15 908 ± 5.36 0.76 ± 0.03 2.52 ± 0.15 17.7 ± 0.15 17.3 ± 0.30 0.40 ± 0.17 0.37 ± 0.12 0.10 ± 0.02 0.53 ± 0.01
N5 670 ± 1.22 2.12 ± 0.01 36.6 ± 0.11 840 ± 1.36 0.41 ± 0.01 1.19 ± 0.05 37.9 ± 0.15 29.5 ± 0.05 0.58 ± 0.17 0.56 ± 0.03 0.19 ± 0.01 0.74 ± 0.01
N6 1400 ± 15.50 5.42 ± 0.05 42.8 ± 0.32 1440 ± 12.2 1.10 ± 0.07 3.60 ± 0.02 16.2 ± 0.35 15.4 ± 0.05 0.53 ± 0.19 0.38 ± 0.02 0.11 ± 0.01 0.69 ± 0.02
N7 6500 ± 40.07 12.8 ± 0.10 217 ± 1.03 7400 ± 21.3 2.47 ± 0.02 11.7 ± 0.05 31.9 ± 0.50 58.3 ± 0.25 2.39 ± 0.15 0.95 ± 0.21 0.25 ± 0.01 4.25 ± 0.05
N8 6400 ± 6.87 13.4 ± 0.10 183 ± 0.35 7340 ± 23.6 2.70 ± 0.05 10.5 ± 0.05 30.4 ± 0.20 63.2 ± 0.10 3.07 ± 0.22 1.66 ± 0.35 0.26 ± 0.02 4.90 ± 0.25
N9 4300 ± 13.34 52.0 ± 0.28 130 ± 0.69 4600 ± 31.0 2.17 ± 0.01 14.24 ± 0.1 13.8 ± 0.15 42.7 ± 0.05 1.39 ± 0.10 1.04 ± 0.15 0.15 ± 0.01 1.87 ± 0.02
N10 4500 ± 15.89 17.6 ± 0.15 178 ± 0.90 2130 ± 13.7 2.39 ± 0.05 9.98 ± 0.20 20.5 ± 0.20 49.8 ± 0.10 2.08 ± 0.05 1.67 ± 0.35 0.22 ± 0.03 4.27 ± 0.05
N11 3200 ± 15.10 8.17 ± 0.06 104 ± 0.20 3800 ± 11.5 1.62 ± 0.01 6.41 ± 0.10 14.9 ± 0.10 32.4 ± 0.25 1.74 ± 0.17 0.52 ± 0.04 0.14 ± 0.01 4.06 ± 0.05
N12 2420 ± 16.20 8.53 ± 0.01 77.5 ± 0.35 2440 ± 10.9 1.27 ± 0.02 6.09 ± 0.13 11.3 ± 0.05 23.4 ± 0.11 1.32 ± 0.12 1.31 ± 0.01 2.00 ± 0.01 2.44 ± 0.02
N13 5600 ± 30.05 78.8 ± 0.15 189.8 ± 1.2 6900 ± 56.3 2.90 ± 0.07 23.5 ± 0.26 20.9 ± 0.15 48.4 ± 0.25 1.89 ± 0.20 0.37 ± 0.02 0.21 ± 0.02 2.29 ± 0.01
IN1 2340 ± 23.20 11.4 ± 0.05 128.5 ± 1.0 2930 ± 22.1 1.30 ± 0.01 7.36 ± 0.06 12.6 ± 0.03 45.3 ± 0.43 1.33 ± 0.08 0.67 ± 0.24 0.65 ± 0.04 2.54 ± 0.04
IN2 1300 ± 12.80 4.80 ± 0.06 98.5 ± 0.75 1500 ± 11.8 0.74 ± 0.01 4.32 ± 0.24 12.2 ± 0.05 66.9 ± 0.32 1.08 ± 0.20 0.77 ± 0.43 0.61 ± 0.02 1.80 ± 0.03
IN3 2100 ± 16.14 9.06 ± 0.47 124 ± 0.70 2900 ± 19.1 1.25 ± 0.01 5.37 ± 0.05 13.1 ± 0.15 40.5 ± 0.30 1.81 ± 0.17 0.57 ± 0.03 0.62 ± 0.02 2.89 ± 0.05
Chewing tobacco products
G1 111.27 ± 8.17 0.69 ± 0.07 27.37 ± 0.7 176.96 ± 5 BDL 1.50 ± 0.07 16.0 ± 0.55 9.15 ± 0.27 BDL 1.03 ± 0.11 BDL 0.08 ± 0.00
G2 736.6 ± 24.90 10.44 ± 0.3 40.0 ± 1.03 762.1 ± 20 0.45 ± 0.02 9.27 ± 0.51 17.5 ± 0.42 17.07 ± 0.6 BDL BDL BDL 0.18 ± 0.01
G3 454 ± 14.70 1.95 ± 0.10 41.87 ± 0.9 563.1 ± 13 0.19 ± 0.00 2.75 ± 0.17 16.0 ± 0.29 47.72 ± 1.1 BDL 0.21 ± 0.04 BDL 1.85 ± 0.07
G4 542.7 ± 20.70 1.12 ± 0.09 51.07 ± 1.3 580.2 ± 14 0.06 ± 0.01 1.46 ± 0.15 14.68 ± 0.4 35.75 ± 1.1 BDL 0.07 ± 0.01 BDL 3.96 ± 0.16