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Table 3 Validation of the micro-wave assisted digestion method against certified reference material (Oriental tobacco leaves, CTA-OTL-1), n = 6

From: Quantitative analysis of some important metals and metalloids in tobacco products by inductively coupled plasma-mass spectrometry (ICP-MS)

Element

Certified value ± S.D. (μg/g)

Recovered value ± S.D. (μg/g)

% R.S.D.

% Recovery

27Al

252 ± 49

264.03 ± 5.14

3.29

104.77

52Cr

0.991a

1.07 ± 0.07

5.42

107.97

55Mn

136 ± 5

141.59 ± 3.2

2.85

104.11

56Fe

258a

248.11 ± 4.77

2.76

96.17

59Co

0.154b ± 0.007

0.167b ± 0.009

5.73

108.44

60Ni

1.49 ± 0.14

1.525 ± 0.076

1.64

102.35

65Cu

5.12 ± 0.2

5.48 ± 0.02

4.8

107.03

66Zn

43.6 ± 1.4

44.85 ± 0.05

1.99

102.87

75As

0.138b ± 0.01

0.144b ± 0.01

3

104.35

82Se

NAc

BDLd

NAc

NAc

111Cd

2.23 ± 0.12

2.386 ± 0.005

4.78

106.99

208Pb

0.972b ± 0.147

0.965b ± 0.028

0.51

99.28

  1. a Information value; b ng/g; c Not available; d Below detection limit.