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Table 1 Hydrogen bond geometry for {[Cu(pydc)(amp)].3H2O}n

From: Supramolecular assembled of hexameric water clusters into a 1D chain containing (H2O)6 and [(H2O)4O2] stabilized by hydrogen bonding in a copper complex

D-H...A

d(D-H)

d(H...A)

d(D...A)

<(DHA)

Symmetry

operations

N4-H4NA...O3

0.90

1.89

2.744(4)

157

 

N4-H4NB...N3

0.90

2.14

3.036(5)

175

1-x, 1-y, -z

O1W-H1WA...O4

0.85

2.02

2.851(4)

165

 

O(1W)-(1WB)...O3W

0.85

1.97

2.790(4)

163

1-x, 1-y, 1-z

O2W-H2WA...O1W

0.85

1.96

2.771(4)

164

 

O2W-H2WB...O2

0.85

2.04

2.866(4)

163

1+x, y, 1+z

O3W-H3WB...O2W

0.85

1.90

2.744(4)

176

 

O3W-H3WA...O4

0.85

2.05

2.827(4)

152

1+x, y, z

C3-H3A...O2

0.95

2.29

3.226(6)

167

-1-x, 2-y, -z

C11- H11A...O1

0.95

2.31

2.96395)

126

 

C11- H11A...O3W

0.95

2.41

3.122(5)

131

-1+x, y, -1+z