Table 1 13C (125 MHz) and1H (500 MHz) NMR spectroscopic data for 1 in DMSO-d6.
position | δH | δC |
|---|---|---|
1 | 130.4 | |
2 | 6.65 (1H, d, J = 2.0 Hz) | 115.7 |
3 | 146.3 | |
4 | 145.8 | |
5 | 6.60(1H, d, J = 8.0 Hz) | 112.4 |
6 | 6.80(1H, d, J = 8.0 Hz) | 118.7 |
7 | 2.75(2H, t, J = 8.2 Hz) | 29.4 |
8 | 3.27(2H, t, J = 8.2 Hz) | 45.4 |
9 | 204.9 | |
1' | 105.3 | |
2' | 162.9 | |
3' | 6.00(1 H, s) | 94.8 |
4' | 163.7 | |
5' | 6.00(1 H, s) | 94.8 |
6' | 162.9 | |
OCH3 | 3.70 (3H, s) | 55.7 |
1" | 5.08 (1H, d, J = 7.0 Hz) | 97.1 |
2" | 3.50 | 77.1 |
3" | 3.34 | 76.5 |
4" | 3.50 | 69.4 |
5" | 3.37 | 76.8 |
6" | 3.50~3.65 | 60.3 |
1"' | 5.04 (1H, br s) | 100.6 |
2"' | 3.82 | 70.4 |
3"' | 3.02 | 70.5 |
4"' | 3.02 | 71.9 |
5"' | 3.82 | 68.3 |
6"' | 1.25 (3H, d, J = 7.0 Hz) | 18.1 |