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Table 5 Activation parameters for the neutral hydrolysis of methyl trifluoroacetate in H2O/DMSO

From: On the curvature in logarithmic plots of rate coefficients for chemical reactions

a

Δu TS / kcal mol-1

σ

35

(4.14 10-2)

0.50

(1.71 10-3)

29.19

(2.30 10-2)

2.36 10-3

(2.94 10-5)

0.70

(2.73 10-4)