Table 4 Activation parameters for the solvolysis of methyldiphenylsulfonium ion in H2O and EtOH
From: On the curvature in logarithmic plots of rate coefficients for chemical reactions
Solvent | a |
| Δu TS / kcal mol-1 | σ |
|
|---|---|---|---|---|---|
H2O | 1 | 3.36 1010 (1.22 1010) | 26.51 (0.22) | 4.04 10-2 (1.06 10-2) | 2.57 10-2 (2.13 10-4) |
EtOH | 77 (13.75) | 1.00 10-2 (3.48 10-2) | 72.51 (8.76) | 1.01 10-2 (4.98 10-3) | 0.69 (3.87 10-2) |
