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Table 3 Activation parameters for the rearrangement of bis-(4-chlorophenyl) thioncarbonate to bis-(4-chlorophenyl) thiolcarbonate (without solvent)

From: On the curvature in logarithmic plots of rate coefficients for chemical reactions

a

Δu TS / kcal mol-1

σ

85

2.02 10-1

125.29

6.61 10-3

0.72