Skip to main content

Table 2 Activation parameters for the hydrolysis of trans-dinitrobis(ethylenediamine) cobalt III ion

From: On the curvature in logarithmic plots of rate coefficients for chemical reactions

Acid a Δu TS / kcal mol-1 σ
HBr 3.547 M 120
(6.87)
0.24
(6.87 10-2)
94.42
(4.25)
1.47 10-2
(5.13 10-3)
0.81
(1.02 10-2)
H2SO4 2.575 M 82
(3.62)
0.66
(0.23)
70.69
(2.20)
7.08 10-2
(4.69 10-3)
0.73
(9.65 10-3)
HNO3 6.148 M 28
(2.92)
2.70 102
(8.95 102)
36.19
(1.77)
5.83 10-2
(4.59 10-3)
0.48
(2.58 10-2)
  1. Standard deviations are given in parentheses.
\