Table 2 Activation parameters for the hydrolysis of trans-dinitrobis(ethylenediamine) cobalt III ion
From: On the curvature in logarithmic plots of rate coefficients for chemical reactions
Acid | a |
| Δu TS / kcal mol-1 | σ |
|
|---|---|---|---|---|---|
HBr 3.547 M | 120 (6.87) | 0.24 (6.87 10-2) | 94.42 (4.25) | 1.47 10-2 (5.13 10-3) | 0.81 (1.02 10-2) |
H2SO4 2.575 M | 82 (3.62) | 0.66 (0.23) | 70.69 (2.20) | 7.08 10-2 (4.69 10-3) | 0.73 (9.65 10-3) |
HNO3 6.148 M | 28 (2.92) | 2.70 102 (8.95 102) | 36.19 (1.77) | 5.83 10-2 (4.59 10-3) | 0.48 (2.58 10-2) |
