Table 2 Activation parameters for the hydrolysis of trans-dinitrobis(ethylenediamine) cobalt III ion
From: On the curvature in logarithmic plots of rate coefficients for chemical reactions
| Acid | a |
| Δu TS / kcal mol-1 | σ |
|
|---|---|---|---|---|---|
| HBr 3.547 M |
120 (6.87) |
0.24 (6.87 10-2) |
94.42 (4.25) |
1.47 10-2 (5.13 10-3) |
0.81 (1.02 10-2) |
| H2SO4 2.575 M |
82 (3.62) |
0.66 (0.23) |
70.69 (2.20) |
7.08 10-2 (4.69 10-3) |
0.73 (9.65 10-3) |
| HNO3 6.148 M |
28 (2.92) |
2.70 102 (8.95 102) |
36.19 (1.77) |
5.83 10-2 (4.59 10-3) |
0.48 (2.58 10-2) |
