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Table 12 Activation parameters for the solvolysis of 4-methylbenzhydryl 4-nitrobenzoate in 90% acetone

From: On the curvature in logarithmic plots of rate coefficients for chemical reactions

a

Δu TS / kcal mol-1

σ

6

(5.15 10-2)

1.06 106

(3.50 104)

29.95

(8.16 10-2)

3.15 10-2

(4.12 10-3)

0.14

(8.36 10-4)

  1. Standard deviations are given in parentheses.