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Table 11 Activation parameters for the hydration of carbon dioxide in water

From: On the curvature in logarithmic plots of rate coefficients for chemical reactions

Reaction a Δu TS / kcal mol-1 σ
CO2 + H2O 30
(16.35)
1.50 102
(2.61 103)
35.95
(9.70)
5.76 10-2
(2.38 10-2)
0.49
(0.10)
CO2 + OH- 1 1.95 1015
(4.49 1014)
15.33
(0.13)
1.02 10-1
(1.27 10-2)
0.038
(3.28 10-4)
  1. Standard deviations are given in parentheses.
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