Table 11 Activation parameters for the hydration of carbon dioxide in water
From: On the curvature in logarithmic plots of rate coefficients for chemical reactions
| Reaction | a |
| Δu TS / kcal mol-1 | σ |
|
|---|---|---|---|---|---|
| CO2 + H2O |
30 (16.35) |
1.50 102 (2.61 103) |
35.95 (9.70) |
5.76 10-2 (2.38 10-2) |
0.49 (0.10) |
| CO2 + OH- | 1 |
1.95 1015 (4.49 1014) |
15.33 (0.13) |
1.02 10-1 (1.27 10-2) |
0.038 (3.28 10-4) |
