Table 11 Activation parameters for the hydration of carbon dioxide in water
From: On the curvature in logarithmic plots of rate coefficients for chemical reactions
Reaction | a |
| Δu TS / kcal mol-1 | σ |
|
|---|---|---|---|---|---|
CO2 + H2O | 30 (16.35) | 1.50 102 (2.61 103) | 35.95 (9.70) | 5.76 10-2 (2.38 10-2) | 0.49 (0.10) |
CO2 + OH- | 1 | 1.95 1015 (4.49 1014) | 15.33 (0.13) | 1.02 10-1 (1.27 10-2) | 0.038 (3.28 10-4) |
