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Table 4 Thermodynamic and kinetic parametersa of the copper(II)- isatinic complexes.

From: The ligational behavior of an isatinic quinolyl hydrazone towards copper(II)- ions

Complex

Stage

T (K)

A × 10-9sec-1

E*

ΔH*

ΔG*

-ΔS*

1

1st

592

1.709 × 107

71.952

67.038

31.487

-60.053

2

1st

355

1.486

5.942

2.996

28.082

70.667

 

2nd

475

5.627

9.123

5.18

34.644

62.029

4

1st

590

9.601

10.914

6.017

41.059

59.393

5

1st

602

14.053

12.281

7.284

41.235

56.398

  1. a E*, ΔH* and ΔG* are in k J mol-1 while ΔS* is in J mol-1 K-1.
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BMC Chemistry

ISSN: 2661-801X

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