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Table 2 700 MHz Proton-Proton Nuclear Overhauser Interaction Peaks a for Cyclopamine in CD2Cl2 at 25°C

From: Isolation, purification, and full NMR assignments of cyclopamine from Veratrum californicum

No.b Atom 1 Atom 2 Relationship
1 1 ax 3 ax-ax
2 1 ax 9 ax-ax
3 2 ax 4 ax ax-ax
4 2 ax 19 ax-ax
5 4 eq 6 eq-eq
6 8 19 ax-ax
7 8 7 e ax-eq
8 8 15 ax ax-ax
9 9 7 ax ax-eq
10 9 14 ax-ax
11 16 eq 23 eq-ax
12 16 ax 14 ax-ax
13 18 20 eq-eq
14 18 22 eq-ax
15 19 1 ax ax-ax
16 19 4 ax ax-ax
17 19 11 ax ax-ax
18 20 22 eq-ax
19 21 16 eq ax-eq
20 21 16 ax ax-ax
21 21 23 ax-ax
22 24 eq 23 eq-ax
23 24 ax 18 (vwc) ax-eq
24 24 ax 26 ax ax-ax
25 24 ax 22 ax-ax
26 24 ax 23 (vwc) ax-eq
27 26 ax 22 ax-ax
28 25 23 ax-ax
29 25 24 eq ax-eq
30 25 26 eq ax-eq
31 27 24 eq eq-eq
32 27 24 ax eq-ax
33 27 26 eq eq-eq
34 27 26 ax eq-ax
35 20 16 ax (vwc) eq-ax
36 8 11 ax ax-ax
  1. aOnly the NOEs that were used to obtain hydrogen and stereochemical assignments are included.
  2. bNumbering scheme corresponds to NOESY peaks identified in Additional files 3, 4, 5.
  3. cvery weak